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Electrolytic refining. Electrolysis, or electrolytic refining, is a technique that is already in use for the extraction and purification of metals, and it is a much more cost-effective and efficient technique than traditional heat-based smelting methods.
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In electrolytic refining, impure tin is cast into anodes. These are placed into an acidic electrolyte with starting cathodes made of thin sheets cast from high-purity tin. Special agents are required in the electrolyte in order to obtain dense, compact cathode deposits. After a period of about a week, the cathodes are removed.
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The commercial production of electrolytic metals had its origin a century ago when James Elkington, an English electroplater, invented a process for refining copper electrolytically; later, about 1890, aluminum was first produced on a commercial scale by electrolysis, followed by lead in 1905, nickel in 1910, and zinc about 1915.
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